Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes
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چکیده
منابع مشابه
Halogen effects on photoluminescence and catalytic properties: a series of spatially arranged trimetallic zinc(II) complexes.
Self-assembly of ZnX2 (X = Cl, Br, and I) with N,N',N''-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide (L) as a tridentate N-donor ligand yields discrete C3-symmetric trimetallic zinc(II) complexes, [Zn3X6L(MeOH)3]. These form, via π∙∙∙π interactions and NH∙∙∙∙O=C hydrogen-bonds, an ensemble constituting a unique columnar stacking structure in an abab staggered fashion. For this series of c...
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Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalys...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2020
ISSN: 1434-1948
DOI: 10.1002/ejic.201901335